Experimental Investigation of Ammonia/Oxygen/Argon Combustion: The Role of Equivalence Ratio and Nozzle Shape in a Constant Volume Combustion Chamber with Sub-chamber
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The global rise in carbon emissions presents a rising challenge for current and future generations. In the pursuit of zero carbon emissions, ammonia (NH3) has emerged as an attractive alternative energy source. Ammonia offers a carbon-free fuel option with a higher energy density than liquid hydrogen while maintaining ease of transport and storage. However, ammonia still has its drawbacks, such as a high autoignition temperature, slow burning velocity, and low heating value, that demand further investigation of its combustion characteristics. This experiment was done to study the effect of nozzle shape and equivalence ratio (ɸ) on the combustion of an ammonia/oxygen/argon mixture using a constant volume combustor equipped with a sub-chamber. The fuels were premixed for 10 minutes and conditioned to an initial pressure of 0.2 MPa and an initial mixture temperature of 423 K. The results show that the different nozzle shapes each have their advantages in terms of pressure and jet speed. Overall, the lean mixtures (ɸ0.6 and ɸ0.8) consistently performed better compared to the stoichiometric mixtures (ɸ1.0) in all categories investigated in this study. The round nozzle generates higher pressure, while the special shape nozzle enhances jet speed, highlighting trade-offs between the two.
CO2 Emissions in 2022 – Analysis – IEA, 2022, International Energy Agency. https://www.iea.org/reports/co2-emissions-in-2022 (October 24, 2023)
Net Zero Coalition | United Nations. n.d., For a Livable Climate: Net-Zero Commitments Must be Backed by Credible Action, https://www.un.org/en/climatechange/net-zero-coalition (October 24, 2023)
Azis, M., Wijayanta, A.T. & Nandiyanto, A.B.D., Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization, Energies, 13(12), 3062, 2020. doi: 10.3390/en13123062
Wahyu, M., Rahmad, H. & Gotama, G.J., Effect of Cassava Biogasoline on Fuel Consumption and CO Exhaust Emissions, Automotive Experiences, 2(3), pp. 97-103, 2019.
Marlina, E., Basjir, M., Ichiyanagi, M., Suzuki, T., Gotama, G.J. & Anggono, W., The Role of Eucalyptus Oil in Crude Palm Oil as Biodiesel Fuel, Automotive Experiences, 3(1), pp. 33-38, 2020.
Hayakawa, A., Goto, T., Mimoto, R., Arakawa, Y., Kudo, T. & Kobayashi, H., Laminar Burning Velocity and Markstein Length of Ammonia/Air Premixed Flames at Various Pressures, Fuel, 159, pp. 98-106, 2015. doi: 10.1016/j.fuel.2015.06.070.
Koike, M., Miyagawa, H., Suzuoki, T. & Ogasawara, K., Ammonia as a Hydrogen Energy Carrier and its Application to Internal Combustion Engines, Sustainable Vehicle Technologies, pp. 61-70, 2012.
Ghavam, S., Vahdati, M., Wilson, I.A.G. & Styring, P., Sustainable Ammonia Production Processes, Sustainable Ammonia Production Processes, Front. Energy Res., 9, 580808, 2021.
Sun, X., Li, M., Li, J., Duan, X., Wang, C., Luo, W., Liu, H. & Liu, J., Nitrogen Oxides and Ammonia Removal Analysis Based on Three-dimensional Ammonia-diesel Dual Fuel Engine Coupled with One-dimensional SCR Model, Energies, 16(2), 908, 2023. doi:10.3390/en16020908
Elbaz, A.M., Wang, S., Guiberti, T.F. & Roberts, W.L., Review on the Recent Advances on Ammonia Combustion from the Fundamentals to the Applications, Fuel Communications, 10, 100053, 2022.
Han, X., Wang, Z., Costa, M., Sun, Z., He, Y. & Cen, K., Experimental and Kinetic Modeling Study of Laminar Burning Velocities of NH3/Air, NH3/H2/Air, NH3/CO/Air and NH3/CH4/Air Premixed Flames, Combust Flame, 206, pp. 214–226, 2019.
Guo, B., Ichiyanagi, M., Kajiki, K., Aratake, N., Zheng, Q., Kodaka, M. & Suzuki, T., Combustion Analysis of Ammonia Fueled High Compression Ratio SI Engine with Glow Plug and Sub-chamber -Effects of Ammonia Content under Condition of Co-combustion with Gasoline/Ammonia/Air-, Int. J. Automot. Eng., 13(1), pp. 1-8, 2022.
Takeishi, H., Hayashi, J., Kono, S., Arita, W., Iino, K. & Akamatsu, F., Characteristics of Ammonia/N2/O2 Laminar Flame in Oxygen-Enriched Air Condition, Trans. JSME, 81(824), 14-00423, 2015.
Ohta, T., Onishi, Y. & Sakai, Y., Modulation of Wall Turbulence by Propagating Flame of Premixed Hydrogen–air Combustion, Combust Flame, 241, 112132, 2022.
Nakano, H., Kobayashi, S., Sako, T., Nishimura, K. & Ishiyama, T., Research on Effect of Sub-chamber in Natural Gas Lean Burn Engine, Trans. Soc. Automot. Eng. Jpn., 47(4), pp. 843-848, 2016.
Guo, B., Ichiyanagi, M., Horie, M., Aihara, K., Ohashi, T., Zhang, A. & Suzuki, T., Combustion Analysis of Ammonia/Oxygen Mixtures at Various Equivalence Ratio Conditions Using a Constant Volume Combustor with Sub-chamber, Automotive Experiences, 4(3), pp. 161-170, 2021.
Guo, B., Ichiyanagi, M., Ohashi, T., Zheng, Q. & Suzuki, T., Effect of Equivalence Ratio and Mixing Time on Combustion of Ammonia/ Oxygen/Argon Mixture using a Constant Volume Combustion Chamber with Sub-chamber, Journal of Mechanical Science and Technology, 37(7), pp. 3829-3840, 2023.
Ohashi, T., Guo, B., Zhengi, Q., Sanno, M., Ichiyanagi, M. & Suzuki, T., Effect of Equivalence Ratio and Nozzle Diameter on Combustion of Ammonia/Oxygen/Argon Mixture using a Constant Volume Combustion Chamber with Sub-chamber, JSAE KANTO International Conference of Automotive Technology for Young Engineers (ICATYE), Tokyo, Japan, 2023.
Rahman, M.S., Tay, G.F.K. & Tachie, M.F., Effects of Nozzle Geometry on Turbulent Characteristics and Structure of Surface Attaching Jets. Flow, Turbulence and Combustion, 103, pp. 797-825, 2019. doi: 10.1007/s10494-019-00047-7
Xia, Y., Hashimoto, G., Hadi, K., Hashimoto, N., Hayakawa, A., Kobayashi, H. & Fujita, O., Turbulent Burning Velocity of Ammonia/Oxygen/Nitrogen Premixed Flame in O2-enriched Air Condition, Fuel, 268, p. 117383, 2020. doi:10.1016/j.fuel.2020.117383
Mathieu, O. & Petersen, E.L., Experimental and Modeling Study on the High-temperature Oxidation of Ammonia and Related Nox Chemistry, Combustion and flame, 162(3), pp. 554-570, 2015.
He, X., Shu, B., Nascimento, D., Moshammer, K., Costa, M. & Fernandes, R.X., Auto-Ignition Kinetics of Ammonia and Ammonia/Hydrogen Mixtures at Intermediate Temperatures and High Pressures, Combustion and Flame, 206, pp. 189-200, 2019.
Ilbas, M., Kekul, O., Bektas, A. & Karyeyen, S., Oxidizer Effects on Ammonia Combustion Using a Generated Non-Premixed Burner, International Journal of Hydrogen Energy, 47(24), pp. 12317-12337, 2022. doi: 10.1016/j.ijhydene.2021.05.105.
Dong, P., Chen, S., Dong, D., Wei, F., Lu, M., Wang, P. & Long, W., Future Zero Carbon Ammonia Engine: Fundamental Study on the Effect of Jet Ignition System Characterized by Gasoline Ignition Chamber, Journal of Cleaner Production, 435, p. 140546, 2024.
Kanoshima, R., Hayakawa, A., Kudo, T., Okafor, E.C., Colson, S., Ichikawa, A., Kudo, T. & Kobayashi, H., Effects of Initial Mixture Temperature and Pressure on Laminar Burning Velocity and Markstein Length of Ammonia/Air Premixed Laminar Flames, Fuel, 310, 122149, 2022.
Hashimoto, G., Hadi, K., Xia, Y., Hamid, A., Hashimoto, N., Hayakawa, A., Kobayashi, H., & Fujita, O., Turbulent Flame Propagation Limits of Ammonia/Methane/Air Premixed Mixture in a Constant Volume Vessel, Proceedings of the Combustion Institute, 38(4), pp. 5171-5180, 2021. doi: 10.1016/j.proci.2020.08.055.
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